{N′-[(E)-(5-Bromo-2-oxidophenyl)(phenyl)methylene]-4-chlorobenzohydrazidato}pyridinenickel(II)
نویسندگان
چکیده
The asymmetric unit of title complex, [Ni(C(20)H(12)BrClN(2)O(2))(C(5)H(5)N)], contains one complex with the central Ni atom in a slightly distorted square-planar environment, formed by the tridentate hydrazone and the monodentate pyridine ligands, with N atoms in a trans arrangement about the Ni atom.
منابع مشابه
{N′-[(E)-(5-Bromo-2-oxidophenyl)(phenyl)methylene]benzohydrazidato}pyridinenickel(II)
The asymmetric unit of title complex, [Ni(C(20)H(13)BrN(2)O(2))(C(5)H(5)N)], contains two independent mol-ecules. In each mol-ecule, the central Ni(II) atom has a square-planar environment, formed by the tridentate hydrazone and the monodentate pyridine ligands, with the N atoms in a trans arrangement about the Ni(II) atom.
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The asymmetric unit of title complex, [Cu(C(20)H(13)BrN(2)O(2))(C(5)H(5)N)], contains two independent mol-ecules. In each mol-ecule, the central Cu(II) atom has a square-planar environment formed by the tridentate hydrazone and the monodentate pyridine ligands, with the N atoms in a trans arrangement about the Cu(II) atom.
متن کامل{N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene]-4-hydroxybenzohydrazidato}pyridinecopper(II)
In the title complex, [Cu(C(15)H(11)BrN(2)O(3))(C(5)H(5)N)], the central Cu(II) atom is in a square-planar CuN(2)O(2) coordination environment formed by the tridentate hydrazone and the monodentate pyridine ligands with N atoms in a trans-arrangement about the Cu(II) atom.
متن کامل{N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene]-4-chlorobenzohydrazidato}pyridinenickel(II)
The title complex, [Ni(C(15)H(10)BrClN(2)O(2))(C(5)H(5)N)], displays a square-planar coordination geometry around the Ni(II) ion, formed by the tridentate hydrazone and monodentate pyridine ligands, with the N atoms in a trans arrangement about the Ni center.
متن کامل{N′-[(E)-1-(5-Bromo-2-oxidophenyl)ethylidene-κO]-4-methylbenzohydrazidato-κ2 N′,O}(pyridine-κN)nickel(II)
The central Ni(II) atom in the title complex, [Ni(C(16)H(13)BrN(2)O(2))(C(5)H(5)N)], is in a square-planar trans-N(2)O(2) environment defined by the NO(2) donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine mol-ecule forms a dihedral angle of 9.99 (11)° with the least-squares plane through the NiN(2)O(2) atoms.
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